Wednesday, March 6, 2019
Diamond and Graphite
In mineralogy,  adamant (from the ancient Greek   adamas unbreakable) is an allotrope of century, where the  vitamin C atoms argon arranged in a variation of the face-centered cubic  watch glasslizing structure called a  rhomb lattice. ball field is renowned as a  cancel with superlative physical qualities, most of which originate from the strong covalent bonding  amid its atoms. In particular,  rhombus has the  mellowedest  warmness and  thermal  conduction of any bulk material. ELECTRICAL CONDUCTANCE  Diamond is less  enduring than   plumbago,  unless the conversion rate from  baseball diamond to black lead is negligible at  close conditions. Other specialized applications also exist or argon  world developed, including use as semiconductors some  blue diamonds  atomic number 18 natural semiconductors, in contrast to most diamonds, which are excellent electrical insulators. The  conduction and blue color originate from boron impurity. Boron substitutes for  one C atoms in the diamo   nd lattice, donating a hole into the valence band.Substantial conductivity is  usually observed in nominally undoped diamond grown by chemical vapor deposition. This conductivity is associated with hydrogen- associate species adsorbed at the surface, and it  basis be removed by annealing or  other(a) surface  swear outment HARDNESS  Diamond is the hardest natural material known, where hardness is outlined as  exsertance to scratching and is graded between 1 (softest) and 10 (hardest) using the Mohs scale of mineral hardness. Diamond has a hardness of 10 (hardest) on this scale.Diamonds hardness has been known since antiquity, and is the source of its name. Diamond hardness depends on its purity, crystalline perfection and orientation hardness is  high for flawless, pure crystals oriented to the direction (along the longest diagonal of the cubic diamond lattice). Therefore, whereas it might be possible to scratch some diamonds with other materials, such(prenominal) as boron nitride,    the hardest diamonds can only be scratched by other diamonds and nanocrystalline diamond aggregates. The hardness of diamond contributes to its suitability as a gemst atomic number 53.Because it can only be scratched by other diamonds, it maintains its polish extremely well. unalike many other gems, it is well-suited to daily wear because of its resistance to scratchingthe hardest natural diamonds mostly originate from the Copeton and Bingara fields located in the New England  theater in New South Wales, Australia. These diamonds are  generally small, perfect to semiperfect octahedra, and are used to polish other diamonds. Their hardness is associated with the crystal growth  descriptor, which is single-stage crystal growth.Most other diamonds show  more(prenominal) evidence of multiple growth stages, which  let out inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness. It is possible to treat regular diamonds under a combination of high pre   ssure and high temperature to produce diamonds that are harder than the diamonds used in hardness gauges.  close to related to hardness is another mechanical property toughness, which is a materials ability to resist breakage from forceful impact. The toughness of natural diamond has been measured as 2. MPam1/2, and the critical stress intensity factor is 3. 4MNm? 3/2. Those values are good compared to other gemstones, but  abject compared to most engineering materials. As with any material, the macroscopic geometry of a diamond contributes to its resistance to breakage. Diamond has a cleavage plane and is therefore more fragile in some orientations than others. Diamond cutters use this attribute to  mystify some stones, prior to faceting. USES  The market for industrial-grade diamonds operates much differently from its gem-grade counterpart.Industrial diamonds are  set mostly for their hardness and heat conductivity, making many of the gemological characteristics of diamonds, such    as clarity and color, irrelevant for most applications. This helps explain why 80% of  tap diamonds (equal to about 135,000,000carats (27,000 kg) annually), un fitting for use as gemstones, are destined for industrial use. In addition to mined diamonds,  man-made diamonds found industrial applications  or so immediately after their invention in the 1950s another 570,000,000carats (110,000 kg) of synthetic diamond is produced annually for industrial use.Approximately 90% of diamond grinding  mother wit is currently of synthetic origin. The boundary between gem-quality diamonds and industrial diamonds is poorly defined and partly depends on market conditions (for example, if demand for polished diamonds is high, some suitable stones will be polished into low-quality or small gemstones rather than  be sold for industrial use). Within the category of industrial diamonds, there is a sub-category comprising the lowest-quality, mostly opaque stones, which are known as bort. Graphite is a b   lack opaque solid with metallic shine.It is very soft and feels greasy.  buttery feeling of graphite is due to ease with which layers can slide one over the other in graphite. The mineral graphite is one of the allotropes of  atomic number 6. It was named by Abraham Gottlob Werner in 1789 from the Greek  (graphein) to draw/write, for its use in pencils, where it is commonly called lead (not to be confused with the metallic element lead). Unlike diamond (another  coke allotrope), graphite is an electrical conductor, a semimetal. Graphite is the most stable form of carbon under standard conditions.Therefore, it is used in thermo  chemical science as the standard state for defining the heat of formation of carbon compounds. Graphite may be considered the highest grade of coal, just above anthracite and alternatively called meta-anthracite, although it is not normally used as fuel because it is hard to ignite. There are three principal types of natural graphite, each occurring in differ   ent types of ore deposit 1. Crystalline flake graphite (or flake graphite for short) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken and when broken the edges can be  unsteady or angular 2.Amorphous graphite occurs as fine particles and is the result of thermal metamorphism of coal, the last stage of coalification, and is sometimes called meta-anthracite. Very fine flake graphite is sometimes called amorphous in the trade 3. Lump graphite (also called vena graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of  unchewable or acicular crystalline aggregates, and is probably hydrothermal in origin. ELECTRICAL CONDUCTANCE  Somewhat of a surprise is that at surface temperatures and pressures, Graphite is the stable form of carbon.In fact, all diamonds at or near the surface of the Earth are currently undergoing a transformation into Graphite. This reaction, fortunately, is extremely slow. Graphite intercalation compoun   ds (GICs) are complex materials having formula XC y  the in-plane electrical conductivity generally increases. HARDNESS  These are the most common types of pencils, and are encased in wood. They are made of a mixture of clay and graphite and their  fantasm varies from light grey to black. Their composition allows for the smoothest strokes.As the name implies, these are solid sticks of graphite, USES   inhering graphite is mostly consumed for refractories, steelmaking, expanded graphite, brake linings, foundry facings and lubricant. Graphene, which occurs naturally in graphite, has unique physical properties and might be one of the strongest substances known however, the  butt on of separating it from graphite will require some technological development  earlier it is economically feasible to use it in industrial processes.Graphite (carbon)  part and carbon nanotubes are also used in carbon fiber  strengthened plastics, and in heat-resistant composites such as reinforced carbon-carbo   n (RCC). Products made from carbon fiber graphite composites include fishing rods, golf clubs, bicycle frames, and pool  discriminative stimulus sticks and have been successfully employed in reinforced concrete. The mechanical properties of carbon fiber graphite-reinforced plastic composites and grey cast iron are  potently influenced by the role of graphite in these materials.In this context, the term (100%) graphite is  oft loosely used to refer to a pure mixture of carbon reinforcement and resin, while the term composite is used for composite materials with  additive ingredients. 21 Graphite has been used in at least three  radio detection and ranging absorbent materials. It was mixed with rubber in Sumpf and Schornsteinfeger, which were used on  hero snorkels to reduce their radar cross section. It was also used in tiles on early F-117 Nighthawks. Modern smokeless powder is coated in graphite to prevent the buildup of static charge.  
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